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Abstract Changes in the Atlantic Meridional Overturning Circulation (AMOC) are believed to have affected the cycling of carbon isotopes in both the ocean and the atmosphere. However, understanding how AMOC changes of Dissolved Inorganic Carbon (DIC) distributions in the ocean is limited, since models do not typically decompose the various processes that affect . Here, a new decomposition is applied to idealized simulations of an AMOC collapse, both for glacial and preindustrial conditions. The decomposition explicitly calculates the preformed and regenerated components of and separates between physical and biological effects. An AMOC collapse leads to a large and rapid decrease in in the North Atlantic, which is due to, in about equal parts, accumulation of remineralized organic matter and changes in preformed , both in glacial and preindustrial simulations. In the Pacific, Indian, and Southern Oceans increases by a smaller magnitude. This increase is dominated by changes in preformed in the glacial simulation and remineralized in the preindustrial simulation. An extensive evaluation of the decomposition shows that its errors are small in most cases, especially for large basin‐wide changes, whereas for small, local or global changes errors can be substantial. In contrast, approximations of the remineralized component based on Apparent Oxygen Utilization have large errors in most cases and are generally unreliable because they include contributions from oxygen disequilibrium. 

The Atlantic Meridional Overturning Circulation (AMOC) impacts temperatures, ecosystems, and the carbon cycle. However, AMOC effects on Earth's carbon cycle remains poorly understood, in part because contributions of different physical and biological mechanisms that impact carbon storage in the ocean are not typically diagnosed in climate models. Here, we explore modeled effects of AMOC shutdowns on ocean Dissolved Inorganic Carbon (DIC) by applying a new decomposition that explicitly calculates preformed and regenerated DIC components and separates physical and biological contributions. An extensive evaluation in transient simulations finds that the method is accurate, especially for basin‐wide changes, whereas errors can be significant at global and local scales. In contrast, estimates of respired carbon based on Apparent Oxygen Utilization lead to large errors and are generally not reliable. In response to a shutdown of the AMOC under Last Glacial Maximum (LGM) background climate, ocean carbon increases and then decreases, leading to opposite changes in atmospheric carbon dioxide (CO2). DIC changes are dominated by opposing changes in biological carbon storage. Whereas regenerated components increase in the Atlantic and dominate the initial increase in global ocean DIC until model year 1000, preformed components decrease in the other ocean basins and dominate the long‐term DIC decrease until year 4000. Biological disequilibrium is an important contribution to preformed carbon changes. Biological saturation carbon decreases in the Pacific, Indian, and Southern Oceans due to a decrease in surface alkalinity. The spatial patterns of the DIC components and their changes in response to an AMOC collapse are presented. 

The prevailing hypothesis for lower atmospheric carbon dioxide (CO 2 ) concentrations during glacial periods is an increased efficiency of the ocean’s biological pump. However, tests of this and other hypotheses have been hampered by the difficulty to accurately quantify ocean carbon components. Here, we use an observationally constrained earth system model to precisely quantify these components and the role that different processes play in simulated glacial-interglacial CO 2 variations. We find that air-sea disequilibrium greatly amplifies the effects of cooler temperatures and iron fertilization on glacial ocean carbon storage even as the efficiency of the soft-tissue biological pump decreases. These two processes, which have previously been regarded as minor, explain most of our simulated glacial CO 2 drawdown, while ocean circulation and sea ice extent, hitherto considered dominant, emerge as relatively small contributors. 

Abstract At present, tides supply approximately half (1 TW) of the energy necessary to sustain the global deep meridional overturning circulation (MOC) through diapycnal mixing. During the Last Glacial Maximum (LGM; 19,000–26,500 years BP), tidal dissipation in the open ocean may have strongly increased due to the 120‐ to 130‐m global mean sea level drop and changes in ocean basin shape. However, few investigations into LGM climate and ocean circulation consider LGM tidal mixing changes. Here, using an intermediate complexity climate model, we present a detailed investigation on how changes in tidal dissipation would affect the global MOC. Present‐day and LGM tidal constituents M₂, S₂, K₁, and O₁are simulated using a tide model and accounting for LGM bathymetric changes. The tide model results suggest that the LGM energy supply to the internal wave field was 1.8–3 times larger than at present and highly sensitive to Antarctic and Laurentide ice sheet extent. Including realistic LGM tide forcing in the LGM climate simulations leads to large increases in Atlantic diapycnal diffusivities and strengthens (by 14–64% at 32°S) and deepens the Atlantic MOC. Increased input of tidal energy leads to a greater drawdown of North Atlantic Deep Water and mixing with Antarctic Bottom Water altering Atlantic temperature and salinity distributions. Our results imply that changes in tidal dissipation need be accounted for in paleoclimate simulation setup as they can lead to large differences in ocean mixing, the global MOC, and presumably also ocean carbon and other biogeochemical cycles. 

Abstract Decades of observations show that the world's oceans have been losing oxygen, with far‐reaching consequences for ecosystems and biogeochemical cycling. To reconstruct oxygenation beyond the limited scope of instrumental records, proxy records are needed, such as sedimentary δ¹⁵N. We combine two δ¹⁵N records from the Santa Barbara Basin (SBB), a 24‐year‐long, biweekly sediment trap time series, and a 114‐year, high‐resolution sediment core together spanning the years 1892–2017. These records allow for the examination of δ¹⁵N variability on seasonal to centennial timescales. Seasonal variability in SBB δ¹⁵N is consistent in timing with the poleward advection of a high δ¹⁵N signal from the Eastern Tropical North Pacific in the summer and fall. Strong El Niño events result in variable δ¹⁵N signatures, reflective of local rainfall, and neither the Pacific Decadal Oscillation nor North Pacific Gyre Oscillation impose strong controls on bulk sedimentary δ¹⁵N. Seasonal and interannual variability in sediment trap δ¹³C_orgis consistent with local productivity as a driver; however, this signal is not retained in the sediment core. The time series from the sediment trap and core show that bulk sedimentary δ¹⁵N in SBB has now exceeded that measured for the past 2,000 years. We hypothesize that the change in δ¹⁵N reflects the increasing influence of denitrified waters from the Eastern Tropical North Pacific and ongoing deoxygenation of the Eastern Pacific. When juxtaposed with other regional δ¹⁵N records our results further suggest that SBB is uniquely situated to record long‐term change in the Eastern Tropical North Pacific.